When signing up on the newly created Empyreus site (thank you!), the user creation form asks for my main character information - yet, after I have signed up, the character isn't associated with my account. My suggestion is that you hide that field when admin intervention is required to associate characters with accounts
The association request has been entered on your site, so the admin just need to approve the request. The fields are serving their purpose, though perhaps a notification of "The character association request needs to be approved before you'll be able to edit it" would be helpful.
Edit: I've gone ahead and completed the association request.
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It's all in the reflexes.